Tremaine Research Group
Tremaine Research Group
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Publications

 

All publications can be viewed on ORCID at

https://orcid.org/0000-0002-9722-9180

 

Recent Refereed Journal Articles

 
  • Wolf MW, Sasidharanpillai S, Tremaine PR Determination of the Ionization Constant of the Hydroxyl Group of Glycolic Acid from 5 to 45 °C by Raman Spectroscopy. J. Solution Chem. 2024, 53, 126-143.
  • Arcis H, Conrad JK, Ferguson JP, Erickson KM, Tremaine PR First Ionization Constant of Phosphoric Acid and of Acetic Acid in H2O and D2O from T = 373 K to 573 K at p = 11.5 and 20 MPa by AC Conductivity Methods. J. Solution Chem. 2024, 53, 91-125.
  • Wang P, Anderko A, Tremaine PR Speciation and Phase Equilibria of Aqueous Boric Acid and Alkali Metal Borates from Ambient to Hydrothermal Conditions: A Comprehensive Thermodynamic Model. Ind. Eng. Chem. Res. 2023, 62 (48), 20875-20898.
  • Arcis H, Lee CA, Zimmerman GH, Tremaine PR Critical Review of Transport Properties of HCl, KOH and NaOH in High Temperature Water and Correlations for the Transport Properties of H3O+ and OH-. J. Phys. Chem. Ref. Data 2023, 52, 023103.
  • Sasidharanpillai S, Cox JS, Pye C, Tremaine PR A Raman Spectroscopic and Ab Initio Investigation of Aqueous Boron Speciation under Alkaline Hydrothermal conditions: Evidence for the Structure and Thermodynamic Stability of Diborate Ion. Dalton Transactions 2023, 52, 18391-18406.
  • Alcorn CD, Cox JS, Applegarth L, Tremaine PR In-Situ Experimental Observation and Determination of Speciation in Phase-Separated Mixtures of Aqueous Uranyl Sulfate and Sulfuric Acid under Hydrothermal Conditions by Raman Spectroscopy. J. Supercritical Fluids 2023, 196, 105832.
  • Chvedov D, Trevani L, Tremaine PR Thermodynamics of the Sodium-Iron-Phosphate-Water System under Hydrothermal Conditions II: The Solubility and Gibbs Energy of Formation of Maricite (NaFeIIPO4) from 220 to 300oC. J. Solution Chem. 2023, 52, 731-753.
  • Arcis H, Plumridge J, Tremaine PR Limiting Conductivities of Strong Acids and Bases in D2O and H2O: Deuterium Isotope Effects on Proton Hopping over a Wide Temperature Range. J. Phys. Chem. B 2023, 126 (43), 8791-8803.
  • Conrad JK, Arcis H, Ferguson JP, Tremaine PR Second Ionization Constant of Sulfuric Acid in H2O and D2O from 150 to 300°C at p = 11.5 MPa Using Flow AC Conductivity. Phys. Chem. Chem. Phys. 2023, 25, 1659–1676.
  • Yacyshyn M, Applegarth L, Cox JS, Tremaine PR (2022) Deuterium Isotope Effects on the Second Ionization Constant of Aqueous Sulfuric Acid from 25 °C to 200 °C using Raman Spectroscopy. J. Solution Chem. 2022, 51, 479-498.
  • Fandiño O, Cox JS, McGregor C, Conrad J, Liao K, Tremaine PR Carbon Dioxide Contamination of Aqueous Morpholine Solutions and Effects on Secondary Coolant Chemistry Under CANDU Conditions. Nucl. Tech. 2021, 208 (1), 192-201.
  • Binkley S, Fandiño O, Cox JS, Tremaine PR Standard Partial Molar Heat Capacities and Volumes of Aqueous N,N-Dimethylethanolamine and N,N-Dimethylethanolammonium Chloride from 283.15 to 393.15 K, and Ionization Constants to 598.15 K.  J. Chem. Eng. Data 2021, 66 (11), 4180-4192.
  • Conrad J, Tremaine PR Third Dissociation Constant of Phosphoric Acid in H2O and D2O from 75 to 300 °C at p = 20 MPa using Raman Spectroscopy and a Titanium-Sapphire Flow Cell. Phys. Chem. Chem. Phys. 2021, 23, 10670 – 10685.
  • Arcis H, Ferguson J, Cox JS, Tremaine PR The Ionization Constant of Water at Elevated Temperatures and Pressures: New Data from Direct Conductivity Measurements and Revised Formulations from T = 273 K to 674 K and p = 0.1 MPa to 31 MPa. J. Phys. Chem. Ref. Data 2020, 43, 033103.  See also accompanying ‘Editor’s Pick’ Scilight.
  • Conrad J, Sasidharanpillai S, Tremaine PR Second Dissociation Constant of Carbonic Acid in H2O and D2O from 150 to 325°C at p = 21 MPa using Raman Spectroscopy and a Sapphire-Windowed Flow Cell. J. Phys. Chem. B 2020, 124 (13), 2600-2617.
  • Alcorn CD, Cox JS, Applegarth LMSGA, Tremaine PR Investigation of Uranyl Sulfate Complexation under Hydrothermal Conditions by Quantitative Raman Spectroscopy and Density Functional Theory. J. Phys. Chem. B 2019, 123 (34), 7385–7409.
  • Sasidharanpillai S, Arcis H, Trevani L, Tremaine PR Triborate Formation Constants and Polyborate Speciation under Hydrothermal Conditions by Raman Spectroscopy using a Titanium/Sapphire Flow Cell. J. Phys. Chem. B 2019, 123 (24), 5147-5159.
  • McGregor C, Al-Abdul-Wahid MS, Robertson V, Cox JS, Tremaine PR Formation Constants and Conformational Analysis of Carbamate in Aqueous Solutions of 2-Methylpiperidine and CO2 from 283 K to 313 K by NMR Spectroscopy. J. Phys. Chem. B 2018, 122 (39), 9178-9190.
  • Fandiño O, Sasidharanpillai S, Soldatov DV, Tremaine PR Carbamate formation in the system (2-Methylpiperidine + Carbon Dioxide) by Raman spectroscopy, X-Ray diffraction and computational Studies. J. Phys. Chem. B 2018, 122 (48), 10880-10893. 
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